1. **Problem statement:** We want to find the concentration of CO_2 in ppm that causes the ocean pH to drop from 8.3 to 7.8.
2. **Given relation:**
$$[H^+] = \sqrt[3]{\frac{K_1^2 K_2 P_{CO_2}^2}{2 K_H^2 K_{sp}}}$$
3. **Recall pH definition:**
$$pH = -\log_{10} [H^+]$$
4. **Calculate initial [H^+] at pH 8.3:**
$$[H^+]_{8.3} = 10^{-8.3}$$
5. **Calculate new [H^+] at pH 7.8:**
$$[H^+]_{7.8} = 10^{-7.8}$$
6. **From the relation, since all constants are fixed,**
$$[H^+] \propto P_{CO_2}^{2/3}$$
7. **Set up ratio:**
$$\frac{[H^+]_{7.8}}{[H^+]_{8.3}} = \left(\frac{P_{CO_2,new}}{P_{CO_2,old}}\right)^{2/3}$$
8. **Plug in values:**
$$\frac{10^{-7.8}}{10^{-8.3}} = \left(\frac{P_{CO_2,new}}{420}\right)^{2/3}$$
9. **Simplify left side:**
$$10^{8.3 - 7.8} = 10^{0.5} = \sqrt{10} \approx 3.162$$
10. **Raise both sides to the power of $\frac{3}{2}$ to solve for $\frac{P_{CO_2,new}}{420}$:**
$$\left(3.162\right)^{\frac{3}{2}} = \frac{P_{CO_2,new}}{420}$$
11. **Calculate:**
$$3.162^{1.5} = 3.162 \times \sqrt{3.162} \approx 3.162 \times 1.778 = 5.623$$
12. **Find new CO_2 concentration:**
$$P_{CO_2,new} = 420 \times 5.623 = 2360.7$$
13. **Report answer to 2 significant figures:**
$$\boxed{2400}$$ ppm
This matches the given approximate answer and shows the CO_2 concentration needed to cause a half unit drop in pH.
Co2 Ph Drop E866D7
Step-by-step solutions with LaTeX - clean, fast, and student-friendly.