1. **State the problem:** Calculate the enthalpy change $\Delta H$ for the reaction:
$$\mathrm{CO_{(g)} + NO_{(g)} \rightarrow CO_2{(g)} + \frac{1}{2} N_2{(g)}}$$
2. **Given reactions and their enthalpy changes:**
- Equation A: $$\mathrm{CO_{(g)} + \frac{1}{2} O_2{(g)} \rightarrow CO_2{(g)}} \quad \Delta H_A = -383.0$$
- Equation B: $$\mathrm{N_2{(g)} + O_2{(g)} \rightarrow 2 NO_{(g)}} \quad \Delta H_B = 280.6$$
3. **Goal:** Use Hess's Law, which states that the enthalpy change of a reaction is the sum of enthalpy changes of steps that lead to it.
4. **Manipulate given equations to match the target reaction:**
- Reverse Equation B to get $$\mathrm{2 NO_{(g)} \rightarrow N_2{(g)} + O_2{(g)}}$$ which changes the sign of $\Delta H_B$:
$$\Delta H = -280.6$$
- Divide this reversed equation by 2 to get:
$$\mathrm{NO_{(g)} \rightarrow \frac{1}{2} N_2{(g)} + \frac{1}{2} O_2{(g)}}$$
with enthalpy change:
$$\Delta H = \frac{-280.6}{2} = -140.3$$
5. **Add Equation A and the modified Equation B:**
$$\mathrm{CO_{(g)} + \frac{1}{2} O_2{(g)} \rightarrow CO_2{(g)}} \quad (\Delta H = -383.0)$$
$$\mathrm{NO_{(g)} \rightarrow \frac{1}{2} N_2{(g)} + \frac{1}{2} O_2{(g)}} \quad (\Delta H = -140.3)$$
Adding these:
$$\mathrm{CO_{(g)} + NO_{(g)} + \frac{1}{2} O_2{(g)} \rightarrow CO_2{(g)} + \frac{1}{2} N_2{(g)} + \frac{1}{2} O_2{(g)}}$$
Cancel $\frac{1}{2} O_2{(g)}$ on both sides:
$$\mathrm{CO_{(g)} + NO_{(g)} \rightarrow CO_2{(g)} + \frac{1}{2} N_2{(g)}}$$
6. **Calculate total enthalpy change:**
$$\Delta H = -383.0 + (-140.3) = -523.3$$
**Final answer:**
$$\boxed{\Delta H = -523.3}$$
This means the reaction releases 523.3 units of enthalpy (kJ) and is exothermic.
Enthalpy Change A257D2
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