1. **State the problem:** We have a galvanic cell with zinc (Zn) as the anode and copper (Cu) as the cathode. The cell diagram is given as $$\text{Zn(s)} | \text{ZnSO}_4(\text{aq}) || \text{CuSO}_4(\text{aq}) | \text{Cu(s)}$$.
2. **Identify the half-reactions:**
- At the anode (oxidation): $$\text{Zn(s)} \rightarrow \text{Zn}^{2+} + 2e^-$$
- At the cathode (reduction): $$\text{Cu}^{2+} + 2e^- \rightarrow \text{Cu(s)}$$
3. **Explain electron flow:** Electrons flow from the zinc anode to the copper cathode through the external circuit (voltmeter).
4. **Role of salt bridge:** The salt bridge containing KCl maintains electrical neutrality by allowing ion flow between the two half-cells.
5. **Overall cell reaction:** Combining the half-reactions, the net reaction is:
$$\text{Zn(s)} + \text{Cu}^{2+} \rightarrow \text{Zn}^{2+} + \text{Cu(s)}$$
6. **Summary:** Zinc is oxidized, losing electrons, and copper ions are reduced, gaining electrons, generating an electric current measurable by the voltmeter.
This explains the galvanic cell operation and electron flow clearly.
Galvanic Cell F1C0E3
Step-by-step solutions with LaTeX - clean, fast, and student-friendly.