1. The problem involves understanding the solubility and precipitation of compounds formed by the cations Cu^{2+} and Na^{+} with the anions SO_4^{2-} and OH^{-}.
2. The table shows the products formed when these ions combine:
- Cu^{2+} + SO_4^{2-} \rightarrow CuSO_4 (R, aqueous)
- Na^{+} + SO_4^{2-} \rightarrow Na_2SO_4 (P, aqueous)
- Cu^{2+} + OH^{-} \rightarrow Cu(OH)_2 (P, solid)
- Na^{+} + OH^{-} \rightarrow NaOH (R, aqueous)
3. Here, "R" indicates the compound remains dissolved (reactant or soluble), and "P" indicates a precipitate forms (product or insoluble).
4. The key concept is solubility rules:
- Most sulfate salts are soluble except those of heavy metals like Cu^{2+} which may form soluble or slightly soluble compounds.
- Hydroxides of transition metals like Cu(OH)_2 are generally insoluble and precipitate.
- Alkali metal salts like Na_2SO_4 and NaOH are soluble.
5. Therefore, CuSO_4 is soluble (R, aqueous), Na_2SO_4 is soluble (P, aqueous) but marked as product, Cu(OH)_2 precipitates (P, solid), and NaOH is soluble (R, aqueous).
This table helps predict which combinations form precipitates and which remain dissolved in aqueous solution.
Ion Combinations 552067
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