1. **Problem statement:** We are given two numbers: $(ab)_4$ in base 4 and $(ba)_7$ in base 7, where $a$ and $b$ are digits. We want to find the largest possible value of $(a+b)_{10}$ such that $(ab)_4 = (ba)_7$, and find non-zero values of $a$ and $b$ that satisfy this equality or prove none exist.
2. **Express the numbers in base 10:**
- $(ab)_4 = 4a + b$
- $(ba)_7 = 7b + a$
3. **Set the equality:**
$$4a + b = 7b + a$$
4. **Simplify the equation:**
$$4a + b = 7b + a \\ 4a - a = 7b - b \\ 3a = 6b \\ a = 2b$$
5. **Constraints on digits:**
- Since $(ab)_4$ is base 4, digits $a,b$ must be in $\{0,1,2,3\}$.
- Since $(ba)_7$ is base 7, digits $a,b$ must be in $\{0,1,2,3,4,5,6\}$.
- Both $a$ and $b$ are non-zero.
6. **Find valid pairs $(a,b)$:**
- From $a=2b$, and $a,b \in \{1,2,3\}$ (since $a$ must be at most 3 for base 4), possible $b$ values are 1 or 2:
- If $b=1$, then $a=2$ (valid)
- If $b=2$, then $a=4$ (invalid for base 4)
7. **Check the pair $(a,b) = (2,1)$:**
- $(ab)_4 = 4 \times 2 + 1 = 8 + 1 = 9$
- $(ba)_7 = 7 \times 1 + 2 = 7 + 2 = 9$
- Equality holds.
8. **Calculate $(a+b)_{10}$:**
$$a + b = 2 + 1 = 3$$
9. **Conclusion:**
- The largest possible value of $(a+b)_{10}$ is 3.
- The non-zero digits satisfying $(ab)_4 = (ba)_7$ are $a=2$ and $b=1$.
**Final answer:**
$$\boxed{3}$$
Largest Sum 36343E
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